Additive and Non-additive Ligand Effects in Mixed Halide-Carbonyl-Nitrile Osmium Complexes

Synthesis and Characterization of Luminescent Osmium (II) Carbonyl Complexes Based on Chelating Dibenzoylmethane and Halide Ligands Supporting Information

Synthesis and characterization of luminescent osmium(II) carbonyl complexes based on chelating dibenzoylmethanate and halide ligands.

Octahedral Os(II) complexes 1-5 with formula [Os(CO)3X(dbm)] are prepared through utilization of both solid-state pyrolysis and ligand exchange reactions. These complexes exhibit prominent 3pi-pi* phosphorescence with unusually long lifetimes (29-64 micros) and high quantum yields (0.08-0.13).

NQR Spectra and the Secondary Bonding of Chalcogen Halide Complexes

The Cl and Br NQR spectra of chalcogen halide complexes of aluminium, gallium, titanium, zirconium, hafnium, niobium, tantalum, molybdenum, tungsten, rhenium, iron, ruthenium, osmium, iridium, rhodium, platinum, palladium and gold are discussed. Three structure types of these complexes have been distinguished by X-ray structure analysis: type I with AX2 ligand and [MXnAm] coordination polyhedro...

Synthesis and Characterization of Novel Lead (II) Complexes with Schiff Base Iminopyridine Ligand

First, Schiff base iminopyridine ligand has been prepared by the condensation between primary amine, dimethylaniline and active carbonyl group of pyridine carboxaldehyde, then related complexes were synthesized in methanol solution. The ligand and metal complexes have been characterized by elemental analysis, UV, IR, 1 H NMR and 13CNMR spectroscopy. The spectroscopic data of metal complexes ind...

Synthesis and Studies of Spectral and Thermal Properties of Some Mixed Ligand Complexes of Thorium(IV) and Dioxouranium(VI) With Semicarbazones as Primary Ligand and Sulfoxide as Secondary Ligand

The present work describes the studies on the coordination behaviour of 4[N-(benzalidene) amino]antipyrine semicarbazone (BAAPS) (I), 4[N-(furfural)amino]antipyrine semicarbazone (FFAAPS) (II) and 4[N-(cinnamalidene)amino]antipyrine semicarbazone (CAAPS) (III) in presence of dimethyl sulfoxide (DMSO) or diphenyl sulfoxide (DPSO) towards Th4+ and UO22+ salts. All the complexes were isolate...